Yes, just download the TrillerTV Fire TV app and sign in with your TrillerTV account. This will sync your purchase if you've made one. You can also any show directly from the Fire TV app itself.
Important: At this point in time Facebook log in cannot be used on Fire TV. You have to reset your password from https://www.trillertv.com/account/signin/ and enter your Facebook email. Use the new password to sign in.